トップ›研究者を探す›精密有機合成手法によるキラル遷移金属錯体の触媒的不斉合成法の開発

精密有機合成手法によるキラル遷移金属錯体の触媒的不斉合成法の開発

KAKEN 科学研究費助成事業データベース で見る
研究課題番号 KAKENHI-PROJECT-24655039
研究種目 挑戦的萌芽研究
研究分野 理工系
化学
基礎化学
無機化学
研究機関 北海道大学
代表研究者 小笠原 正道
研究期間 開始年月日 2012/4/1
研究期間 終了年度 2013
研究ステータス 完了 (2013/4/1)
配分額（合計） 4,160,000 (直接経費 :3,200,000、間接経費 :960,000)
配分額（履歴） 2013年度：2,080,000 (直接経費 :1,600,000、間接経費 :480,000)
2012年度：2,080,000 (直接経費 :1,600,000、間接経費 :480,000)
キーワード 有機金属化学
触媒的不斉合成
均一系触媒
面不斉
メタロセン
アレーンクロム
メタセシス
有機合成
遷移金属錯体
リン原子
中心不斉
モリブデン
軸不斉
金属中心不斉

研究成果

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral (η^6-Arene)chromium Complexes

Ogasawara, M. 2014

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral (η6-Arene)chromium Complexes

Masamichi Ogasawara 2014

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes

Ogasawara, M 2013

[学会発表] Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes and Application to Synthesis of Allenic Natural Products

Ogasawara, M. 2013

[学会発表] Design and Synthesis of Phosphine-Olefin Ligands Having Planar-Chiral (π-Arene)chromium Framework and Application in Asymmetric Catalysis

Masamichi Ogasawara, Wei-Yi Wu, Takeshi Nakaya, Tomotaka Morita, Sachie Arae, Ya-Yi Tseng, Tamotsu Takahashi, Ken Kamikawa 2013

[学会発表] 不斉閉環メタセシス反応によるジヒドロインデニル構造を有する面不斉錯体の触媒的不斉合成

小笠原正道、荒江　祥永、中島　清彦、高橋　保 2013

[学会発表] Catalytic Induction of Planar Chirality in Functional Metallocenes by Mo-Catalyzed Asymmetric Ring-Closing Metathesis

Masamichi Ogasawara, Sachie Arae, Susumu Watanabe, Ayaka Oana, Kiyohiko Nakajima, Tamotsu Takahashi 2013

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene)chromium Complexes by Asymmetric RCM

Masamichi Ogasawara 2013

[学会発表] Catalytic Asymmetric Synthesis of Planar-Chiral Ferrocenes and Their Applications in Optically Active Metallocene-Polymers

Ogasawara, M 2013

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes

Masamichi Ogasawara 2013

[学会発表] 新規不斉有機分子触媒ライブラリーの構築

小笠原正道 2013

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene)chromium Complexes

Masamichi Ogasawara 2013

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene)chromium Complexes

Ogasawara, M 2013

[学会発表] Atropisomeric Chiral Dienes in Asymmetric Catalysis : Design, Synthesis, and Application of C_2-Symmetric (Z,Z)-1,2-Bis[1-(diphenylphosphino)ethylidene]c ycloalkane Derivatives

Ogasawara, M. 2013

[学会発表] Catalytic Enantioselective Synthesis of Planar-Chiral Zirconocenes and Their Application as Chiral Catalysts

Masamichi Ogasawara, Sachie Arae, Ayaka Oana, Wei-Yi Wu, Kiyohiko Nakajima, Tamotsu Takahashi 2013

[学会発表] Design and Synthesis of Phosphine-Olefin Ligands Having Planar-Chiral (π-Arene)chromium Framework and Application in Asymmetric Catalysis

Ogasawara, M 2012

[学会発表] Design and Synthesis of Phosphine-Olefin Ligands Having Planar-Chiral (π-Arene)chromium Framework and Application in Asymmetric Catalysis

Masamichi Ogasawara, Tomotaka Morita, Takeshi Nakaya, Ya-Yi Tseng, Sachie Arae, Wei-Yi Wu, Tamotsu Takahashi, Ken Kamikawa 2012

[学会発表] Catalytic Enantioselective Synthesis of Axially Chiral N-Aryl Indole Chromium Complex by Molybdenum-Catalyzed Asymmetric Desymmetrization

Ken Kamikawa, Sachie Arae, Wei-Yi Wu, Chihiro Nakamura, Tamotsu Takahashi, Masamichi Ogasawara 2012

[学会発表] Helically Chiral Dienes in Asymmetric Catalysis : Design, Synthesis, and Application of 1,4-Bis(phosphino)-1,3-butadiene Derivatives Having C2-C3-Fused Cyclic System

Ogasawara, M 2012

[学会発表] Herically Chiral Dienes in Asymmetric Catalysis : C_2-Symmetric (Z, Z)-1,2-Bis(1-diphenylphosphinylethylidene)cyclo hexanes as Highly Acitve Lewis-Base Organocatalysts

Ogasawara, M 2012

[学会発表]

Ogasawara, M 2012

[雑誌論文] 面不斉遷移金属錯体の触媒的不斉合成

荒江祥永・小笠原正道 2012