トップ研究者を探す新たな設計思想に基づく不斉フェロセニルホスフィン配位子の合成と均一系触媒への応用

新たな設計思想に基づく不斉フェロセニルホスフィン配位子の合成と均一系触媒への応用

KAKEN 科学研究費助成事業データベース で見る
研究課題番号 KAKENHI-PROJECT-21H01940
研究種目 基盤研究(B)
研究分野
研究機関 徳島大学
代表研究者 小笠原 正道
研究期間 開始年月日 2021/4/1
研究期間 終了年度 2023
研究ステータス 交付 (2023/4/1)
配分額(合計) 17,420,000 (直接経費 :13,400,000、間接経費 :4,020,000)
配分額(履歴) 2023年度:5,460,000 (直接経費 :4,200,000、間接経費 :1,260,000)
2022年度:5,460,000 (直接経費 :4,200,000、間接経費 :1,260,000)
2021年度:6,500,000 (直接経費 :5,000,000、間接経費 :1,500,000)
キーワード フェロセン
ホスフィン
均一系触媒
遷移金属錯体
不斉合成反応

研究成果

[雑誌論文] Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis/Kinetic Resolution of Racemic Planar-Chiral 1,1′-Diallylferrocenes

Imazu Haruna、Masaoka Kakeru、Uike Saki、Ogasawara Masamichi 2024

[雑誌論文] Metal-free carbazole-thiophene photosensitizers designed for a dye-sensitized H2-evolving photocatalyst in Z-scheme water splitting

Nakada Akinobu、Yokota Takayuki、Ogura Morihiko、Chang Ninghui、Tomita Osamu、Saeki Akinori、Ogasawara Masamichi、Abe Ryu 2024

[学会発表] Enantioselective Synthesis of Planar-Chiral Ferrocene Derivatives by Asymmetric Metathesis Dimerization of Vinylferrocenes

Masamichi Ogasawara 2023

[学会発表] Palladium-Catalyzed Synthesis of Allenes: Experimental Observations and Theoretical Rationale

Masamichi Ogasawara and Panida Surawatanawong 2023

[学会発表] Palladium-Catalyzed Synthesis of Alkoxyallenes and Their Application in Regioselective Hydroelementation Reactions

MORI Yuki, Hitomi Tsukasa and Masamichi Ogasawara 2023

[学会発表] Asymmetric Metathesis Dimerization of Vinylferrocenes: New Strategy for Preparing Enantiomerically Enriched Planar-Chiral Ferrocenes

Masamichi Ogasawara 2023

[学会発表] Enantioselective Preparation of Planar-Chiral Ferrocenes: Asymmetric Metathesis Dimerization of Vinylferrocenes

Ogasawara Masamichi 2023

[雑誌論文] Asymmetric Metathesis Dimerization/Kinetic Resolution of Racemic Planar-Chiral Vinylphosphaferrocenes

Masaoka Kakeru、Taue Haruka、Wakioka Masayuki、Ohki Yasuhiro、Ogasawara Masamichi 2023

[雑誌論文] Competitive Double Friedel-Crafts 2,5- and 1′,2-Diacylation of Monophosphaferrocenes

Masaoka Kakeru、Taue Haruka、Higaki Tatsuya、Ohki Yasuhiro、Ogasawara Masamichi 2023

[学会発表] Palladium-Catalyzed Synthesis of Alkoxyallenes and Their Application in Regioselective Hydroelementation Reactions

森 勇綺, 人見 牧, 小笠原 正道 2023

[学会発表] Design, Synthesis, and Application of Planar-Chiral Skewed DPPF Derivatives

HIBIKI Okabe and Masamichi Ogasawara 2023

[学会発表] Competitive Double Friedel-Crafts 2,5- and 1',2-Diacylation of Monophosphaferrocenes

Masaoka Kakeru, Taue Haruka, Higaki Tatsuya, Ohki Yasuhiro and Masamichi Ogasawara 2023

[学会発表] Competitive Double Friedel-Crafts 2,5- and 1',2-Diacylation of Monophosphaferrocenes

政岡 翔, 田上 遥, 檜垣 達也, 大木 靖弘, 小笠原 正道 2023

[学会発表] Cs-対称ジビニルフェロセン類の不斉メタセシス不斉二量化/非対称化反応

政岡 翔、田上 遥、小笠原 正道 2022

[学会発表] 面不斉ビニルホスファフェロセン類の立体選択的メタセシス不斉二量化反応

小笠原 正道、田上 遥、政岡 翔、脇岡 正幸、大木 靖弘 2022

[雑誌論文] Application of Polysaccharide-Based Chiral High-Performance Liquid Chromatography Columns for the Separation of Regio-, E/Z-, and Enantio–Isomeric Mixtures of Allylic Compounds

Ohji Takehito、Ohnishi Atsushi、Ogasawara Masamichi 2022

[学会発表] Enantioselective Synthesis of Planar-Chiral Feffocenes by Molybdenum-Catalyzed Metathesis Dimerization/Desymmetrization of Divinylferrocenes

Kakeru Masaoka, Taue Haruka, Ogasawara Masamichi 2022

[学会発表] Diastereo- and Enantioselective Metathesis Dimerization/Kinetic Resolution of Racemic Planar-Chiral Vinylferrocenes

Ogasawara Masamichi 2022

[雑誌論文] Enantioselective Preparation of Planar‐Chiral Transition Metal Complexes by Asymmetric Olefin‐Metathesis Reactions in Metal Coordination Spheres

Ogasawara Masamichi 2021