トップ›研究者を探す›遷移金属錯体触媒を用いるアレンおよび類縁体の合成反応の開発

遷移金属錯体触媒を用いるアレンおよび類縁体の合成反応の開発

KAKEN 科学研究費助成事業データベース で見る
研究課題番号 KAKENHI-PROJECT-17550093
研究種目 基盤研究(C)
研究分野 理工系
化学
複合化学
合成化学
研究機関 北海道大学
代表研究者 小笠原 正道
研究期間 開始年月日 2005/4/1
研究期間 終了年度 2006
研究ステータス 完了 (2006/4/1)
配分額（合計） 3,600,000 (直接経費 :3,600,000)
配分額（履歴） 2006年度：1,800,000 (直接経費 :1,800,000)
2005年度：1,800,000 (直接経費 :1,800,000)
キーワード アレン
パラジウム
軸不斉
触媒的不斉合成
共役ジエン
昆虫フェロモン
アレニルシラン
不斉転写
環状アレン
立体選択性
不斉炭素
allene
palladium
axial chirality
catalytic asymmetric synthesis
conjugated diene
insect pheromone
allenylsilane
chirality transfer

研究成果

[雑誌論文] Preparation and Characterization of 1,1'-Diphosphaferrocenes with Linearly Fused Six-Membered Carbocycles

Masamichi Ogasawara 2007

[雑誌論文] Preparation and Characterization of 1, 1'-Diphosphaferrocenes with Linearly Fused Six-Membered Carbocycles

小笠原 正道 2007

[雑誌論文] Preparation and Characterization of 1,1'-Diphosphaferrocenes with Linearly Fused Six-Membered Carbocycles

小笠原 正道 2007

[雑誌論文] Synthesis of 2,5-Bis(binaphthyl)phospholes and Phosphametallocene Derivatives and Their Application in Pd-Catalyzed Asymmetric Hydrosilylation

Masamichi Ogasawara 2006

[雑誌論文] Synthesis of 2,5-Bis(binaphthyl)-phospholes and Phosphametallocene Derivatives and Their Application in Pd-Catalyzed Asymmetric Hydrosilylation

小笠原 正道 2006

[雑誌論文] Kinetic Resolution of Planar-Chiral Ferrocenes by Mo-Catalyzed Enantioselective Metathesis

Masamichi Ogasawara 2006

[雑誌論文] Palladium-Catalyzed Preparation of Vinylallenes from 2-Bromo-1,3,5-trienes via an Alkylidene-n- allvinalladium-Mediated Formal SN2" Pathway

Masamichi Ogasawara 2006

[雑誌論文] Synthesis of 2,5 -Bis(binaphthyl)-phospholes and Phosphametallocene Derivatives and Their Application in Pd-Catalyzed Asymmetric Hydrosilylation

小笠原 正道 2006

[雑誌論文] Palladium-Catalyzed Preparation of Vinylallenes from 2-Bromo-1,3,5-trienes via an Alkylidene-π-allylpalladium-Mediated Formal S_N2" Pathway

小笠原 正道 2006

[雑誌論文] Kinetic Resolution of Planar-Chiral Ferrocenes by Mo-Catalyzed Enantioselective Metathesis

小笠原 正道 2006

[雑誌論文] Applications of 4,4'-(Me_3Si)_2-BINAP in Transition-Metal-Catalyzed Asymmetric Carbon-Carbon Bond-Forming Reactions

小笠原 正道 2005

[雑誌論文] A New Route to Methyl (R,E)-(-)-Tetradeca-2,4,5-trienoate (Pheromone of Acanthoscelides Obtectus) Utilizing a Palladium-Catalyzed Asymmetric Allene Formation Reaction

小笠原 正道 2005

[雑誌論文] Preparation of Multi-Substituted Allenes from Allylsilanes

小笠原 正道 2005

[雑誌論文] Applications of 4,4'-(Me3Si)2-BINAP in Transition-Metal-Catalyzed Asymmetric Carbon-Carbon Bond-Forming Reactions

Masamichi Ogasawara 2005

[雑誌論文] A New Route to Methyl (R,E)-(-)-Tetradeca-2,4,5-trienoate(Pheromone of Acanthoscelides Obtectus) Utilizing a Palladium-Catalyzed Asymmetric Allene Formation Reaction

小笠原 正道 2005

[雑誌論文] Vinyl Ketones to Allenes : Preparation of 1,3-Dien-2-y1 Triflates and Their Application in Pd-Catalyzed Reaction with Soft Nucleophiles

Masamichi Ogasawara 2005

[雑誌論文] A New Route to Methyl (R, E)-(_)-Tetradeca-2,4,5- trienoate (Pheromone of Acanthoscelides Obtectus) Utilizing a Palladium-Catalyzed Asymmetric Allene Formation Reaction

Masamichi Ogasawara 2005

[雑誌論文] Vinyl Ketones to Allenes : Preparation of 1,3-Dien-2-yl Triflates and Their Application in Pd-Catalyzed Reaction with Soft Nucleophiles

小笠原 正道 2005

[雑誌論文] Preparation of Multi-Substituted Allenes from Allylsilanes

Masamichi Ogasawara 2005

[雑誌論文] Applications of 4,4'-(Me_3Si)_2-BINAP in Transition-Metal- Catalyzed Asymmetric Carbon-Carbon Bond-Forming Reactions

小笠原 正道 2005