トップ研究者を探すシラアレンカチオン活性種及び類縁体の合成開発と応用研究

シラアレンカチオン活性種及び類縁体の合成開発と応用研究

KAKEN 科学研究費助成事業データベース で見る
研究課題番号 KAKENHI-PROJECT-16390008
研究種目 基盤研究(B)
研究分野 生物系
医歯薬学
薬学
化学系薬学
研究機関 徳島大学
代表研究者 長尾 善光
研究分担者 佐野 茂樹
研究期間 開始年月日 2004/4/1
研究期間 終了年度 2006
研究ステータス 完了 (2006/4/1)
配分額(合計) 14,500,000 (直接経費 :14,500,000)
配分額(履歴) 2006年度:1,800,000 (直接経費 :1,800,000)
2005年度:5,000,000 (直接経費 :5,000,000)
2004年度:7,700,000 (直接経費 :7,700,000)
キーワード シラアレン
ジアリルモノアルキニルフルオロシラン
オキサシレタン
アザシレタン
ジアルキニルジアリルシラン
シラシクロブテン
共役ジエン
環化反応
シラレン
シラアレンカチオン
ジアリルアルキニルフルオロシラン
ジアリルジアルキニルシラン
テトラクロロシラン
ジアリルジフルオロシラン
X線結晶構造解析
テトラフルオロシラン
アリルトリクロロシラン
ジアリルジクロロシラン
silaallene
diarylmonoalkynylfluorosilane
dialkynyldiarylsilane
oxasiletane
azasiletane
silacyclobutene
desilylation
conjugated diene

研究成果

[雑誌論文] Expeditious Syntheses of Conjyugated Allenyl Esters and Oxazoles through a Cascade Reaction of α-Alkynyl Malonates under Alkaline Conditions

Yoshimitsu Nagao 2006

[雑誌論文] Expeditious Syntheses of Conjugated Allenyl Esters and Oxazoles through a Cascade Reaction of α-Alkynyl Malonates under Alkaline Conditions

Yoshimitsu Nagao 2006

[雑誌論文] Synthesis of Novel Silacyclobutene Derivatives Utilizing Zirconocene-and Titanocene-Ethylene Complexes

Yoshimitsu Nagao et al. 2006

[雑誌論文] Expeditious Syntheses of Conjugated Allenyl Esters and Oxazoles through a Cascade Reaction of a-Alkynyl Malonates under Alkaline Conditions

Yoshimitsu Nagao et al. 2006

[雑誌論文] Synthesis of Novel Silacyclobutene Derivatives Utilizing Zirconocene-and Titanocene-Ethylene Complexes

Yoshimitsu Nagao 2006

[雑誌論文] Trimethylaluminium-Induced Diastereoselective Methylation onto Ethyl 2- Oxocyclopentane-1-carboxylate and Isomerization between Both of the Dimethylaluminium-Alkoxide Products

Yoshimitsu Nagao et al. 2005

[雑誌論文] Facile Generation Method for Conjugated Allenyl Esters Based on retro-Dieckmann Type Ring-Opening

Yoshimitsu Nagao et al. 2005

[雑誌論文] Trimethylaluminium-Induced Diastereoselective Methylation onto Ethyl 2-Oxocyclopentane-1-carboxylate and Isomerization between Both of the Dimethylaluminium-Alkoxide Products

Yoshimitsu Nagao 2005

[雑誌論文] Facile Generation Method for Conjugated Allenyl Esters Based on retro-Dieckmann Type Ring-Opening

Yoshimitsu Nagao 2005

[雑誌論文] New Synthetic Methods for Seven- and Eight-Membered Cyclic Ethers Based on the Ring-Expansion Reactions of Hydroxy or Lithioxy Methoxyallenylisochroman Derivatives

Yoshimitsu Nagao 2004

[雑誌論文] New Synthetic Methods for Seven-and Eight-Membered Cyclic Ethers Based on the Ring-Expansion Reactions of Hydroxy or Lithioxy Methoxyallenylisochroman Derivatives

Yoshimitsu Nagao 2004

[雑誌論文] Preferential Conformation of the Six-membered Cyclic Compounds Bearing Both Trimethyl-siloxy(or Methoxymethyleneoxy) and Tributyistannyl Groups at the Geminal Position

Yoshimitsu Nagao 2004

[雑誌論文] New Ring-Expansion Reactions of Hydroxy Propenoyl Cyclic Compounds under Palladium(0)/Phosphine-Catalyzed Conditions

Yoshimitsu Nagao 2004

[雑誌論文] Intramolecular Nonbonded S…O Interaction in Acetazolamide and Thiadiazolinethione Molecules in Their Dimeric Crystalline Structures and Complex Crystalline Structures with Enzymes

Yoshimitsu Nagao 2004

[雑誌論文] New Synthetic Methods for Seven-and Eight-Membered Cyclic Ethers Based on the Ring-Expansion Reactions of Hydroxy or Lithioxy Methoxyallenylisochroman Derivatives

Yoshimitsu Nagao et al. 2004

[雑誌論文] Stereoselective Synthesis of Unsymmetrical Conjugated Dienes and Trienes Utilizing Silacyclobutenes

Yoshimitsu Nagao

[雑誌論文] Stereoselective Synthesis of Unsymmetrical Conjugated Dienes and Trienes Utilizing Silacyclobutenes

Yoshimitsu Nagao et al.