トップ研究者を探す三価の超原子価有機臭素化合物を活用する反応の開発とその化学的特性の解明

三価の超原子価有機臭素化合物を活用する反応の開発とその化学的特性の解明

KAKEN 科学研究費助成事業データベース で見る
研究課題番号 KAKENHI-PROJECT-18390005
研究種目 基盤研究(B)
研究分野 生物系
医歯薬学
薬学
化学系薬学
研究機関 徳島大学
代表研究者 落合 正仁
研究分担者 宮本 和範
研究期間 開始年月日 2006/4/1
研究期間 終了年度 2007
研究ステータス 完了 (2007/4/1)
配分額(合計) 17,250,000 (直接経費 :15,300,000、間接経費 :1,950,000)
配分額(履歴) 2007年度:8,450,000 (直接経費 :6,500,000、間接経費 :1,950,000)
2006年度:8,800,000 (直接経費 :8,800,000)
キーワード 超原子価
臭素
ヨウ素
脱離基
加溶媒分解反応
求核置換反応
カチオン
カルベン
チカオン
臭素3
アルキン
Michael付加反応
ジイン
超脱離能
プロマン
Hypervalent
Bromine
Iodine
Leaving group
Solvolysis
Nucleophilic substitution
Cation
Carbene

研究成果

[雑誌論文] Rhodium(II)-Catalyzed Transylidation of Aryliodonium Ylides: Electronic Effects of Aryl Groups Determine Their Thermodynamic Stabilities

Masahito Ochiai 2008

[雑誌論文] Difuoro-λ^3-Bromane-Induced Oxidative Carbon-Carbon Bond-Forming Reactions : Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles

Masahito, Ochiai 2008

[雑誌論文] Difluoro-λ^3-Bromane-lnduced Oxidative Carbon-Carbon Bond-Forming Reactions:Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles

Masahito Ochiai 2008

[雑誌論文] Rhodium(II) -Catalyzed Transylidation of Aryliodonium Ylides : Electronic Effects of Aryl Groups Determine Their Thermodynamic Stabilities

Masahito, Ochiai 2008

[雑誌論文] Difluoro-λ^3-Bromane-Induced Oxidative Carbon-Carbon Bond-Forming Reactions: Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles

Masahito Ochiai 2008

[雑誌論文] Thermal and Catalytic Transylidations between Halonium Ylides and Synthesis and Reaction of Stable Aliphatic Chloronium Ylides

Masahito, Ochiai 2008

[雑誌論文] Rhodium(II)-Catalyzed Transylidation of Aryliodonium Ylides:Electronic Effects of Aryl Groups Determine Their Thermodynamic Stabilities

Masahito Ochiai 2008

[雑誌論文] Thermal and Catalytic Transylidations between Halonium Ylides and Synthesis and Reaction of Stable Aliphatic Chloronium Ylides

Masahito Ochiai 2008

[雑誌論文] A New Type of Imido Group Donor. Synthesis and Characterization of Sulfonylimino-λ^3-bromane that Acts as a Nitrenoid in the Aziridination of Olefins at Room Temperature under Metal-free Conditions

Masahito, Ochiai 2007

[雑誌論文] A New Type of Imido Group Donor: Synthesis and Characterization of Sulfonylimino-λ^3-bromane that Acts as a Nitrenoid in the Aziridination of Olefins at Room Temperature under Metal-free Conditions

Masahito Ochiai 2007

[雑誌論文] Stoichiometric and Catalytic Oxidations with Hypervalent Organo-λ^3-iodanes

Masahito Ochiai 2007

[雑誌論文] A New Type of Imido Group Donor:Synthesis and Characterization of Sulfonylimino-λ^3-bromane that Acts as a Nitrenoid in the Aziridination of Olefins at Room Temperature under Metal free Conditions

Masahito Ochiai 2007

[雑誌論文] Stoichiometric and Catalytic Oxidations with Hypervalent Organo-λ^3-iodanes

Masahito, Ochiai 2007

[雑誌論文] Internal Delivery of Soft Chlorine and Bromine Atoms:Stereoselective Synthesis of(E)-β-Halogenovinyl(ryl)-λ^3-iodanes through Donlino λ^3-Iodanation-1,4-Halogen Shift-Fluorination of Alkynes

Masahito Ochiai 2007

[雑誌論文] Stoichiometric and Catalytic Oxidations with Hypervalent Organo-λ^3-iodanes

Masahito Ochiai 2007

[雑誌論文] Internal Delivery of Soft Chlorine and Bromine Atoms : Stereoselective Synthesis of(E)-13-Halogenovinyl(aryl) -λ^3-iodanes through Domino λ^3-Iodanation-1, 4-Halogen Shift-Fluorination of Alkynes

Masahito, Ochiai 2007

[雑誌論文] Internal Delivery of Soft Chlorine and Bromine Atoms: Stereoselective Synthesis of (E)-β-Halogenovinyl (aryl)-λ^3-iodanes through Domino λ^3-Iodanation-1, 4-Halogen Shift-Fluorination of Alkynes

Masahito Ochiai 2007

[雑誌論文] Trans-Influences on Hypervalent Bonding of Aryl-λ^3-iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones

Masahito Ochiai 2006

[雑誌論文] Intermolecular Hypervalent I(III)O Interactions : A New Driving Force for Complexation of Crown Ethers

Masahito, Ochiai 2006

[雑誌論文] Complexation of Diphenyl (tetrafluoroborato)-λ^3-iodane with Pyridines

Masahito Ochiai 2006

[雑誌論文] Synthesis and Characterization of Bromonium Ylides and Their Unusual Ligand Transfer Reactions with N-Heterocycles

Masahito, Ochiai 2006

[雑誌論文] Trans-Influences on Hypervalent Bonding of Aryl-λ^3-iodanes : Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones

Masahito Ochiai 2006

[雑誌論文] Intermolecular Hypervalent I(III)・・・O Interactions: A New Driving Force for Complexation of Crown Ethers

Masahito Ochiai 2006

[雑誌論文] Trans-Infuences on Hypervalent Bonding of Aryl-λ^3-iodanes : Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones

Masahito, Ochiai 2006

[雑誌論文] Silver Technology for Stabilization of Simple (Z)-Enethiols: Stereoselective Synthesis and Reaction of Silver (Z)-Enethiolates

Masahito Ochiai 2006

[雑誌論文] Intermolecular Hypervalent I(III)・・・O Interactions : A New Driving Force for Complexation of Crown Ethers

Masahito Ochiai 2006

[雑誌論文] Synthesis and Characterization of Bromonium Ylides and Their Unusual Ligand Transfer Reactions with N-Heterocycles

Masahito Ochiai 2006

[雑誌論文] Silver Technology for Stabilization of Simple (Z)-Enethiols : Stereoselective Synthesis and Reaction of Silver (Z)-Enethiolates

Masahito Ochiai 2006

[雑誌論文] Complexation of Diphenyl (tetrafluoroborato)-λ^3-iodane with Pyridines

Masahito Ochiai 2006

[雑誌論文] Complexation of Diphenyl(tetrafuoroborato) -λ^3-iodane with Pyridines

Masahito, Ochiai 2006

[雑誌論文] Silver Technology for Stabilization of Simple(Z)-Enethiols : Stereoselective Synthesis and Reaction of Silver(Z)-Enethiolates

Masahito, Ochiai 2006

[雑誌論文] Synthesis and Characterization of Bromonium Ylides and Their Unusual Ligand Transfer Reactions with N-Heterocycles

Masahito Ochiai 2006