環境調和型新規遷移金属錯体触媒の創製とその革新的環構築反応への高度利用法の開発

トップ›研究者を探す›環境調和型新規遷移金属錯体触媒の創製とその革新的環構築反応への高度利用法の開発

環境調和型新規遷移金属錯体触媒の創製とその革新的環構築反応への高度利用法の開発

代表研究者	近藤輝幸
研究課題番号	KAKENHI-PROJECT-18350050
研究種目	基盤研究(B)
研究分野	理工系化学複合化学合成化学
研究機関	京都大学
研究分担者	和田健司
研究期間開始年月日	2006/4/1
研究期間終了年度	2007
研究ステータス	完了 (2007/4/1)
配分額（合計）	16,430,000 (直接経費 :14,900,000、間接経費 :1,530,000)
配分額（履歴）	2007年度：6,630,000 (直接経費 :5,100,000、間接経費 :1,530,000) 2006年度：9,800,000 (直接経費 :9,800,000)
キーワード	ルテニウムロジウム触媒メタラサイクルアルケン共二量化エチレン三量化合成化学触媒・化学プロセス有機工業化学共付加環化反応原子効率 ruthenium rhodium environmentally benign catalyst metallacycle alkene codimerization ethylene trimerization

研究成果

[学会発表] Novel Synthesis of Ketene Dithioacetals via Ruthenium-catalyzed 1,1Addition of Organic Disulfides to Terminal Alkynes

Takashi Fukuda. Kenji Wada, Take-aki Mitsudo, Teruyuki Kondo 2008

[学会発表] Ru/CeO_2-catalyzed Allyl Transfer Reaction of Homoallyl Alcohols to Aldehydes via Cleavage of a C-C Bond

Hiroki Miura, Masahiro Sai, Saburo Hosokawa, Teruyuki Kondo, Kenji Wada, Masashi Inoue 2008

[学会発表] Ruthenium-catalyzed Selective Codimerization of Alkenes with High AtomEfficiency

Yasuyuki Ura, Hiroshi Tsujita, Daisuke Takagi, Shingo Matsuki, Kenji Wada, Take-aki Mitsudo, Teruyuki Kondo 2008

[学会発表] Novel Synthesis of Ketene Dithioacetals via Ruthenium-catalyzed 1,1-Addition of Organic Disulfides to Terminal Alkynes

Teruyuki Kondo, Takashi Fukuda, Kenji Wada, Take-aki Mitsudo 2007

[雑誌論文] Highly Selective Dimerization of Styrenes and Linear Co-dimerization of Styrenes with Ethylene Catalyzed by a Ruthenium Complex

Teruyuki Komdo, Daisuke Takagi, Hiroshi Tsujita, Yasuyuki Ura, Kenji Wada, Take-aki Mitsudo 2007

[雑誌論文] Synthesis and Characterization of a Novel (μ_3-Oxo)tetraruthenium Cluster

Teruyuki Kondo, Fumiaki Tsunawaki, Toshi-aki Suzuki, Yasuyuki Ura, Kenji Wada, Syuhei Yamaguchi, Hideki Masuda, Kenji Yoza, Motoo Shiro, Take-aki Mitsudo 2007

[雑誌論文] Rhodium-catalyzed Rapid Synthesis of Substituted Phenols from Cyclobutenones and Alkynes or Alkenes via C-C Bond Cleavage

Teruyuki Kondo, Masatsugu Niimi, Masato Nomura, Kenji Wada, Take-aki Mitsudo 2007

[雑誌論文] Regio- and Stereoselective Synthesis of Enamides and Dienamides by Ruthenium-catalyzed Co-oligomerization of N-Vinylamides with Alkenes or Alkynes

Hiroshi Tsujita, Yauyuki Ura, Shingo Matsuki, Kenji Wada, Take-aki Mitsudo, Teruyuki Kondo 2007

[学会発表] Novel Synthesis of Ketene Dithioacetals via Ruthenium-catalyzed 1,1-Addition of Organic Disulfides to Terminal Alkynes

Teruyuki Kondo, Takashi Fukuda, Kenji Wada, Take-aki Mitsudo 2007

[学会発表] Ruthenium Complex-catalyzed Highly Selective Codimerization and Cotrimerization of Alkenes

Hiroshi Tsuiita, Yasuyuki Ura, Kenji Wada, Teruyuki Kondo, Take-aki Mitsudo 2006

[雑誌論文] Selective Synthesis of 2-Pyridones and Pyrimidine-2,4-diones by Neutral Rhodium(I) Complex-catalyzed Cyclocotrimerization of Alkynes and Isocyanates

Teruyuki Kondo, Masato Nomura, Yauyuki Ura, Kenji Wada, Take-aki Mitsudo 2006

[雑誌論文] Ruthenium-catalyzed [2 + 2 + 1] Cocyclization of Isocyanates, Alkynes, and CO Enables the Rapid Synthesis of Polysubstituted Maleimides

Teruyuki Kondo, Masato Nomura, Yasuyuki Ura, Kenji Wada, Take-aki Mitsudo 2006

[雑誌論文] Formation of Divalent Ruthenacycles via Oxidative Cyclization of 1,3,5-Cyclooctatriene with Maleic Anhydride or Maleimides : An Intermediate for the Transition Metal-Mediated [6 + 2] Cycloaddition of 1,3,5-Trienes and Alkenes

Yasuyuki Ura, Taka-aki Utsumi, Hiroshi Tsujita, Kenji Wada, Teruyuki Kondo, Take-aki Mitsudo 2006

[学会発表] Synthesis of Dienamides by Ruthenium-catalyzed Codimerization of N-Vinylamides with Alkynes

Yasuyuki Ura. Shingo Matsuki, Hiroshi Tsujita, Kenji Wada, Teruyuki Kondo, Take-aki Mitsudo 2006