トップ研究者を探す大環状π共役系配位子錯体の階段状積層構造と電子機能

大環状π共役系配位子錯体の階段状積層構造と電子機能

KAKEN 科学研究費助成事業データベース で見る
研究課題番号 KAKENHI-PROJECT-15205018
研究種目 基盤研究(A)
研究分野 理工系
化学
複合化学
機能物質化学
研究機関 北海道大学
代表研究者 稲辺 保
研究分担者 内藤 俊雄
研究分担者 田島 裕之
研究期間 開始年月日 2003/4/1
研究期間 終了年度 2006
研究ステータス 完了 (2006/4/1)
配分額(合計) 48,100,000 (直接経費 :37,000,000、間接経費 :11,100,000)
配分額(履歴) 2006年度:4,550,000 (直接経費 :3,500,000、間接経費 :1,050,000)
2005年度:4,550,000 (直接経費 :3,500,000、間接経費 :1,050,000)
2004年度:16,380,000 (直接経費 :12,600,000、間接経費 :3,780,000)
2003年度:22,620,000 (直接経費 :17,400,000、間接経費 :5,220,000)
キーワード フタロシアニン
π積層構造
部分酸化塩
電気伝導性
結晶構造解析
負の磁気抵抗
二次元π積層構造
Phthalocyanine
π-stacking structure
partially oxidized salt
electrical conductivity
crystal structure
negative magnetoresistance

研究成果

[雑誌論文] (ET)_3(Br_3)_5 : A Metallic Conductor with an Unusually High Oxidation State of ET (ET = Bis(ethylenedithio)tetrathiafulvalene)

H.Minemawari, T.Naito, T.Inabe 2007

[雑誌論文] π-Radical Cationic Salts of Tetrathiafulvalene Derivatives with Pyromellitate

K.Shiono, T.Naito, T.Inabe 2007

[雑誌論文] One-step Synthesis of Partially Oxidized Cobalt(III) Phthalocyanine Salts with Axial Ligands

D.E.C.Yu, H.Imai, M.Ushio, S.Takeda, T.Naito, T.Inabe 2006

[雑誌論文] Charge Disproportionation in Highly One-Dimensional Molecular Conductor TPP[Co(Pc)(CN)_2]_2

N.Hanasaki, K.Masuda, K.Kodama, M.Matsuda, J.Yamazaki, M.Takigawa, J.Yamaura, E.Ohmichi, T.Osada, T.Naito, T.Inabe 2006

[雑誌論文] Photochemical fabrication of molecular devices

T.Naito 2006

[雑誌論文] Phthalocyanine conductors : New trend for crystal and functionality design

T.Inabe, M.Ishikawa, T.Asari, H.Hasegawa, A.Fujita, N.Matsumura, T.Naito T, M.Matsuda, H.Tajima 2006

[雑誌論文] Giant Negative Magnetoresistance Reflecting Molecular Symmetry in Dicyano-(phthalocyaninato)iron Compounds

N.Hanasaki, M.Matsda, T.Tajima, E.Ohmichi, T.Osada, T.Naito, T.Inabe 2006

[雑誌論文] Photochemical fabrication of molecular devices

T.Naito 2006

[雑誌論文] Synthesis, Isolation, and Structural Characterization of the C_<4h> Isomer of Metal(1,2-naphthalocyanine) and its One- Dimensional Conductor of the Axially Substituted Species

E.H.Gacho, H.Imai, R.Tsunasihima, T.Naito, T.Inabe, N.Kobayashi 2006

[雑誌論文] Photochemical fabrication of molecular devices

T.Naito, H.Sugawara, T.Inabe, T.Miyamoto, H.Niimi, K.Asakura 2006

[雑誌論文] Phthalocyanine-phthalocyanine salt crystal : a unique assembly design

Y.Ohtsuka, T.Naito, T.Inabe 2005

[雑誌論文] A new optical doping method toward molecular electronics

T.Naito, T.Inabe, H.Niimi, K.Asakura 2005

[雑誌論文] Nearly Isotropic Two- dimensional Sheets in a Partially Oxidized Co(Pc)(CN)_2 Salt (Pc=phthalocyaninato)

T.Asari, M.Ishikawa, T.Naito, M.Matsuda, H.Tajima, T.Inabe 2005

[雑誌論文] A new optical doping method toward molecular electronics

T.Naito 2005

[雑誌論文] A new optical doping method toward molecular electronics

T.Naito 2005

[雑誌論文] Crystal design of cation-radical salts based on the supramolecular self-organizing arrangement of mellitate anions

T.Inabe, N.Kobayashi, T.Naito 2004

[雑誌論文] Network formation of mellitate anions ([C_6(COO)_6H_<6-n>]^<n->) in the salts with piperidinium derivatives and o-phenylenediammonium

N.Kobayashi, T.Naito, T.Inabe 2004

[雑誌論文] Molecular unit based on metal phthalocyanine ; designed for molecular electronics

M.Matsuda, N.Hanasaki, S.Ikeda, H.Tajima, T.Naito, T.Inabe 2004

[雑誌論文] Novel Phthalocyanine Conductor Containing Two-dimensional Pc Stacks, [PXX]_2[Co(Pc)(CN)_2] (PXX = peri- Xanthenoxanthene, Co(Pc)(CN)2 = Dicyandohthalocyaninato)cohalt(III))

T.Asari, T.Naito, T.Inabe, M.Matsuda, H.Tajima 2004

[雑誌論文] Molecular conductors containing photoreactive species

T.Naito, T.Inabe 2004

[雑誌論文] New Binuclear Copper Complexes [(9S3)Cu(CN)Cu(9S3)]X_n (X=BF_4, n=l; X=TCNQ, n=2) (9S3=1,4,7-trithiacyclononane) : Syntheses, Crystal Structures and Magentic Properties

T.Naito 2004

[雑誌論文] Molecular conductors containing photoreactive species

T.Naito 2004

[雑誌論文] New Binuclear Copper Complexes |(9S3)Cu(CN)Cu(9S3)|X (X=BF_4,n=1;X=TCNQ,n=2)(9S3)=1,4,7-trithiacyclononane):Syntheses, Crystal Structures and Magentic Properties

T.Naito 2004

[雑誌論文] New Binuclear Copper Complexes [(9S3)Cu(CN)Cu(9S3)]X_n (X = BF_4, n=1; X = TCNQ, n = 2) (9S3 = 1,4,7- trithiacyclononane) : Syntheses, Crystal Structures and Magnetic Properties

T.Naito, K.Nishibe, T.Inabe 2004

[雑誌論文] Light-Induced Transformation of Molecular Materials into Devices

T.Naito 2004

[雑誌論文] Light-Induced Transformation of Molecular Materials into Devices

T.Naito, T.Inabe, H.Niimi, K.Asakura 2004

[雑誌論文] Physical properties of electrically conducting and stable molecular neutral radical solid [Co(2,3-Nc)(CN)_2]CH_3CN (2,3-Nc = 2,3- naphthalocyanine)

T.Naito, N.Matsumura, T.Inabe, M.Matsuda, H.Tajima 2004

[雑誌論文] Structural, Electrical, and Magnetic Properties of p-(ET)_7[MnCl_4]_2(1,1,2- C_2H_3Cl_3)_2 (ET = Bis(ethylenedithio)tetrathiafullvalene)

T.Naito, T.Inabe 2004

[雑誌論文] Structural, Electrical, and Magnetic Properties of p- (ET)_7[MnCl_4]_2(1,1,2-C_2H_3Cl_3)_2 (ET=Bis(ethylenedithio)tetrathiafulvalene)

T.Naito 2004

[雑誌論文] Structural, Electrical, and Magnetic Properties of π-(ET)_7|MnCl_4|_2AE(1,1,2-C_2H_3Cl_3)_2(ET=Bis(ethylenedithio)tetrathiafulvalene)

T.Naito 2004

[雑誌論文] A Helical π-Radical-Cation Column in the Double Helix of Mellitate Anions

N.Kobayashi, T.Naito, T.Inabe 2004

[雑誌論文] Molecular conductors containing photoreactive species

T.Naito 2004

[雑誌論文] Light-Induced Transformation of Molecular Materials into Devices

T.Naito 2004

[雑誌論文] Physical properties of electrically conducting and stable molecular neutral radical solid [Co(2,3-Nc)(CN)_2]CH_3CN(2,3-Nc=2,3-naphthalocyanine)

T.Naito 2004

[雑誌論文] Hydrogen- Bond Networks of Mellitate Anions ([C_6(COO)_6H_<6-n>]^<n->) in Salts with Pyridine Derivatives

N.Kobayashi, T.Naito, T.Inabe 2003

[雑誌論文] Contribution of Degenerate Molecular Orbitals to Molecular Orbital Angular Momentum in Molecular Magnet Fe(Pc)(CN)_2

N.Hanasaki, M.Matsuda, H.Tajima, T.Naito, T.Inabe 2003

[雑誌論文] ET_3(MnCl_3)_2(EtOH)_2 : a new organic conductor with a perovskite structure

T.Naito, T.Inabe, T.Akutagawa, T.Hasegawa, T.Nakamura 2003

[雑誌論文] Magnetic Properties of d-n Conducting System, TPP[Fe^<III>_xCo^<III>_<1-x>(Pc)(CN)_2]_2

M.Matsuda, N.Hanasaki, H.Tajima, F.Sakai, T.Naito, T.Inabe 2003

[雑誌論文] Physical Properties of (ET)_3(MnCl_4)(TCE) and the Related Salts

T.Naito 2003

[雑誌論文] Magnetic and optical properties of one- dimensional π-d system with axially substituted iron(III) phthalocyanine

M.Matsuda, N.Hanasaki, H.Tajima, T.Naito, T.Inabe 2003

[雑誌論文] Molecular hexagonal perovskite : a new type of organic-inorganic hybird conductor

T.Naito, T.Inabe 2003

[雑誌論文] One-dimensional p-d electron system in TPP[Fe(Pc)(CN)_2]_2, [PXX] [Fe(Pc)(CN)_2], and (FTMA)_x[Fe(Pc)(CN)_2]Y(CH_3CN) : electron spin resonance and negative magnetoresistance

N.Hanasaki, M.Matsuda, H.Tajima, T.Naito, T.Inabe 2003

[雑誌論文] Torque study of TPP[Fe(Pc)(CN)_2]_2 (TPP = tetraphenyl phosphonium and Pc = phthalocyanine)

N.Hanasaki, M.Matsuda, H.Tajima, T.Naito, T.Inabe 2003

[雑誌論文] Molecular hexagonal perovskite : a new type of organic-inorganic hybird conductor

T.Naito 2003

[雑誌論文] Physical Properties of (ET)_3(MnCl_4)(TCE) and the Related Salts

T.Naito, T.Inabe, T.Akutagawa, T.Hasegawa, T.Nakamura, Y.Hosokoshi, K.Inoue 2003

[雑誌論文] Phthalocyanine-based multi-dimensional conductors

T.Inabe, T.Asari, H.Hasegawa, M.Matsuda, H.E.Gacho, N.Matsumura, S.Takeda, K.Takeda, T.Naito 2003

[雑誌論文] Structure and Physical Properties of Low-Dimensional Molecular Conductors, [PXX][Fe^<III>(Pc)(CN)_2] and [PXX][Co^<III>(Pc)(CN)_2] (PXX = peri- xanthenoxanthene, Pc = phthalocyaninato)

M.Matsuda, T.Asari, T.Naito, T.Inabe, N.Hanasaki, H.Tajima 2003

[雑誌論文] ET_3(MnCl_3)_2(EtOH)_2 : a new organic conductor with a perovskite structure

T.Naito 2003